Point Group D15



D15 E 2C15 2(C15)2 2C5 2(C15)4 2C3 2(C5)2 2(C15)7 15C'2
A1 1 1 1 1 1 1 1 1 1
A2 1 1 1 1 1 1 1 1 -1
E1 2 2cos(2π/15) 2cos(4π/15) 2cos(2π/5) 2cos(8π/15) -1 2cos(4π/5) 2cos(14π/15) 0
E2 2 2cos(4π/15) 2cos(8π/15) 2cos(4π/5) 2cos(14π/15) -1 2cos(2π/5) 2cos(2π/15) 0
E3 2 2cos(2π/5) 2cos(4π/5) 2cos(4π/5) 2cos(2π/5) 2 2cos(2π/5) 2cos(4π/5) 0
E4 2 2cos(8π/15) 2cos(14π/15) 2cos(2π/5) 2cos(2π/15) -1 2cos(4π/5) 2cos(4π/15) 0
E5 2 -1 -1 2 -1 -1 2 -1 0
E6 2 2cos(4π/5) 2cos(2π/5) 2cos(2π/5) 2cos(4π/5) 2 2cos(4π/5) 2cos(2π/5) 0
E7 2 2cos(14π/15) 2cos(2π/15) 2cos(4π/5) 2cos(4π/15) -1 2cos(2π/5) 2cos(8π/15) 0


Additional information

Number of symmetry elements h = 30
Number of classes, irreps n = 9
Abelian group no
Optical Isomerism (Chirality) yes
Polar no
Parity no


Reduce representation to irreducible representations


E 2C15 2(C15)2 2C5 2(C15)4 2C3 2(C5)2 2(C15)7 15C'2



Genrate representation from irreducible representations


A1 A2 E1 E2 E3 E4 E5 E6 E7




Direct products of irreducible representations


Binary products
A1 A2 E1 E2 E3 E4 E5 E6 E7
A1 A1
A2 A2A1
E1 E1E1A1⊕A2⊕E2
E2 E2E2E1⊕E3A1⊕A2⊕E4
E3 E3E3E2⊕E4E1⊕E5A1⊕A2⊕E6
E4 E4E4E3⊕E5E2⊕E6E1⊕E7A1⊕A2⊕E7
E5 E5E5E4⊕E6E3⊕E7E2⊕E7E1⊕E6A1⊕A2⊕E5
E6 E6E6E5⊕E7E4⊕E7E3⊕E6E2⊕E5E1⊕E4A1⊕A2⊕E3
E7 E7E7E6⊕E7E5⊕E6E4⊕E5E3⊕E4E2⊕E3E1⊕E2A1⊕A2⊕E1

Ternary Products
Quaternary Products



Symmetric powers [Γn] of degenerate irreducible representations
Vibrational overtones


irrep 2] 3] 4] 5] 6]
E1 A1⊕E2E1⊕E3A1⊕E2⊕E4E1⊕E3⊕E5A1⊕E2⊕E4⊕E6More
E2 A1⊕E4E2⊕E6A1⊕E4⊕E7E2⊕E5⊕E6A1⊕E3⊕E4⊕E7More
E3 A1⊕E6E3⊕E6A1⊕E3⊕E6A1⊕A2⊕E3⊕E6A1⊕2E3⊕E6More
E4 A1⊕E7E3⊕E4A1⊕E1⊕E7E3⊕E4⊕E5A1⊕E1⊕E6⊕E7More
E5 A1⊕E5A1⊕A2⊕E5A1⊕2E5A1⊕A2⊕2E52A1⊕A2⊕2E5More
E6 A1⊕E3E3⊕E6A1⊕E3⊕E6A1⊕A2⊕E3⊕E6A1⊕E3⊕2E6More
E7 A1⊕E1E6⊕E7A1⊕E1⊕E2E5⊕E6⊕E7A1⊕E1⊕E2⊕E3More



Spherical harmonics and Multipoles
Symmetric Powers of Γxyz


Spherical Harmonics Yl / Multipole Symmetric Power [Γl(xyz)]
l 2l+1 Multipole Symmetry Rank l(xyz)]
s (l=0) 1 Monopole A1 1 A1
p (l=1) 3 Dipole A2⊕E1 3 A2⊕E1
d (l=2) 5 Quadrupole A1⊕E1⊕E2 6 2A1⊕E1⊕E2
f (l=3) 7 Octupole A2⊕E1⊕E2⊕E3 10 2A2⊕2E1⊕E2⊕E3
g (l=4) 9 Hexadecapole A1⊕E1⊕E2⊕E3⊕E4 15 3A1⊕2E1⊕2E2⊕E3⊕E4
h (l=5) 11 Dotricontapole A2⊕E1⊕E2⊕E3⊕E4⊕E5 21 3A2⊕3E1⊕2E2⊕2E3⊕E4⊕E5
i (l=6) 13 Tetrahexacontapole A1⊕E1⊕E2⊕E3⊕E4⊕E5⊕E6 28 4A1⊕3E1⊕3E2⊕2E3⊕2E4⊕E5⊕E6
j (l=7) 15 Octacosahectapole A2⊕E1⊕E2⊕E3⊕E4⊕E5⊕E6⊕E7 36 4A2⊕4E1⊕3E2⊕3E3⊕2E4⊕2E5⊕E6⊕E7
k (l=8) 17 256-pole A1⊕E1⊕E2⊕E3⊕E4⊕E5⊕E6⊕2E7 45 5A1⊕4E1⊕4E2⊕3E3⊕3E4⊕2E5⊕2E6⊕2E7
l (l=9) 19 512-pole A2⊕E1⊕E2⊕E3⊕E4⊕E5⊕2E6⊕2E7 55 5A2⊕5E1⊕4E2⊕4E3⊕3E4⊕3E5⊕3E6⊕3E7
m (l=10) 21 1024-pole A1⊕E1⊕E2⊕E3⊕E4⊕2E5⊕2E6⊕2E7 66 6A1⊕5E1⊕5E2⊕4E3⊕4E4⊕4E5⊕4E6⊕4E7
n (l=11) 23 2048-pole A2⊕E1⊕E2⊕E3⊕2E4⊕2E5⊕2E6⊕2E7 78 6A2⊕6E1⊕5E2⊕5E3⊕5E4⊕5E5⊕5E6⊕5E7
o (l=12) 25 4096-pole A1⊕E1⊕E2⊕2E3⊕2E4⊕2E5⊕2E6⊕2E7 91 7A1⊕6E1⊕6E2⊕6E3⊕6E4⊕6E5⊕6E6⊕6E7
More

First nonvanshing multipole: Quadrupole

Further Reading

  • A. Gelessus, W. Thiel, W. Weber. J. Chem. Educ. 72 505 (1995)
    Multipoles and symmetry




Ligand Field, dn term splitting


Term symbols for electronic configurations dn
dn Term Symbols
d1 = d9 2D
d2 = d8 1S, 1D, 1G, 3P, 3F
d3 = d7 2P, 2D (2), 2F, 2G, 2H, 4P, 4F
d4 = d6 1S (2), 1D (2), 1F, 1G (2), 1I, 3P (2), 3D, 3F (2), 3G, 3H, 5D
d5 2S, 2P, 2D (3), 2F (2), 2G (2), 2H, 2I, 4P, 4D, 4F, 4G, 6S


Term splitting in point group D15
L 2L+1 Term Splitting
S (L=0) 1 A1
P (L=1) 3 A2⊕E1
D (L=2) 5 A1⊕E1⊕E2
F (L=3) 7 A2⊕E1⊕E2⊕E3
G (L=4) 9 A1⊕E1⊕E2⊕E3⊕E4
H (L=5) 11 A2⊕E1⊕E2⊕E3⊕E4⊕E5
I (L=6) 13 A1⊕E1⊕E2⊕E3⊕E4⊕E5⊕E6


Last update November, 13th 2023 by A. Gelessus, Impressum, Datenschutzerklärung/DataPrivacyStatement