Reduction formula for point group S8
Your representation
E |
S8 |
C4 (z) |
(S8)3 |
C2 |
(S8)5 |
(C4)3 |
(S8)7 |
48 |
0.0000 |
0 |
-0.0000 |
0 |
-0.0000 |
0 |
0.0000 |
can be reduced to
Substraction of translational and rotational contributions results in
Force field analysis
Infrared and Raman activities (harmonic approximation)
Method |
A |
B |
E1 |
E2 |
E3 |
Infrared |
- |
+ |
+ |
- |
- |
Raman |
+ |
- |
- |
+ |
+ |
No. 1 : Total number of force constants .
No. 2 : Total number of force constants k.
No. 3 : Total number of nonvanishing force constants k.
Symmetry properties of force field parameters
Force field |
A |
B |
E1 |
E2 |
E3 |
linear |
5 |
5 |
5 |
6 |
5 |
quadratic |
116 |
117 |
110 |
115 |
110 |
cubic |
1660 |
1660 |
1650 |
1662 |
1650 |
quartic |
18663 |
18662 |
18590 |
18655 |
18590 |
Number of independant internal coordinates |
5 |
Literature
- J.K.G. Watson, J. Mol. Spec. 41 229 (1972)
The Numbers of Structural Parameters and Potential Constants of Molecules
Last update November, 13th 2023 by A. Gelessus, Impressum, Datenschutzerklärung/DataPrivacyStatement