## Note on E representations inC8h character table

12 irreducible representations of point group C8h have complex values. 6 two-dimensional real-valued representations E can be constructed as direct sum of the 6 pairs complex plus conjugate complex irreducible representation.

E1g = E1g,a ⊕ E1g,b
E2g = E2g,a ⊕ E2g,b
E3g = E3g,a ⊕ E3g,b
E1u = E1u,a ⊕ E1u,b
E2u = E2u,a ⊕ E2u,b
E3u = E3u,a ⊕ E3u,b

ε=exp(2πi/8)
C8h E C8 C4 (C8)3 C2 (C8)5 (C4)3 (C8)7 i (S8)5 (S4)3 (S8)7 σh S8 S4 (S8)3
Ag 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
Bg 1 -1 1 -1 1 -1 1 -1 1 -1 1 -1 1 -1 1 -1
E1g E1g,a
E1g,b
1
1
ε*
ε*
i
-i
*
*
-1
-1
*
*
-i
i
ε*
ε*
1
1
ε*
ε*
i
-i
*
*
-1
-1
*
*
-i
i
ε*
ε*
E2g E2g,a
E2g,b
1
1
i
-i
-1
-1
-i
i
1
1
i
-i
-1
-1
-i
i
1
1
i
-i
-1
-1
-i
i
1
1
i
-i
-1
-1
-i
i
E3g E3g,a
E3g,b
1
1
*
*
-i
i
ε*
ε*
-1
-1
ε*
ε*
i
-i
*
*
1
1
*
*
-i
i
ε*
ε*
-1
-1
ε*
ε*
i
-i
*
*
Au 1 1 1 1 1 1 1 1 -1 -1 -1 -1 -1 -1 -1 -1
Bu 1 -1 1 -1 1 -1 1 -1 -1 1 -1 1 -1 1 -1 1
E1u E1u,a
E1u,b
1
1
ε*
ε*
i
-i
*
*
-1
-1
*
*
-i
i
ε*
ε*
-1
-1
*
*
-i
i
ε*
ε*
1
1
ε*
ε*
i
-i
*
*
E2u E2u,a
E2u,b
1
1
i
-i
-1
-1
-i
i
1
1
i
-i
-1
-1
-i
i
-1
-1
-i
i
1
1
i
-i
-1
-1
-i
i
1
1
i
-i
E3u E3u,a
E3u,b
1
1
*
*
-i
i
ε*
ε*
-1
-1
ε*
ε*
i
-i
*
*
-1
-1
ε*
ε*
i
-i
*
*
1
1
*
*
-i
i
ε*
ε*

Obviously the E representations are reducible. Nevertheless the E representations are treated often as irreducible representations and are called real-valued or pseudo irreducible representations. One should keep in mind that general statements for character tables fail for real-valued representations. For example:
• The number of irreducible representations is usually equal the number of classes. For point group C8h this statement is true for the complex irreducible representations. The number of real-valued irreducible representations is less than the number of classes.
• The sum of the squared characters of the neutral symmetry element over all irreducible representations is equal to the total number of symmetry elements

#### h = ∑ Χi(E) Χi(E)

This statement is true for the complex irreducible representations but not for the real-valued irreducible representations
• Reduction formula: The occurence of i-th irreducible representation in an reducible representation is given by the well known formula

#### ci = 1/h ∑R nR χi(R)irred χ(R)red

This statement is true for the complex irreducible representations. The norm of the two-dimensional real-valued irreducible representations is 2h (instead of h) meaning that the reduction formula has to be modified:

#### ci(E) = 1/(2h) ∑R nR χi(R)irred χ(R)red = (∑R nR χi(R)irred χ(R)red) / (∑R nR χi(R)irred χi(R)irred)

Last update August, 12th 2020 by A. Gelessus, Impressum, Datenschutzerklärung/DataPrivacyStatement